α-chlorovinylation: Synthesis of 2-chloropropenyl and propargyl alcohols

J R Falck, D. K. Barma, Charles Mioskowski, Thierry Schlama

Research output: Contribution to journalArticle

18 Scopus citations

Abstract

Formal α-chlorovinylation of aldehydes using CH3CCl3/CrCl2 affords 2-chloropropenyl alcohols from which terminal propargyl alcohols are obtained via base induced elimination.

Original languageEnglish (US)
Pages (from-to)2091-2094
Number of pages4
JournalTetrahedron Letters
Volume40
Issue number11
DOIs
StatePublished - Mar 12 1999

Keywords

  • Alcohols
  • Alkenyl halides
  • Alkynes
  • Chromium

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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