A highly selective vanadium catalyst for benzylic C-H oxidation

Ji Bao Xia, Kevin W. Cormier, Chuo Chen

Research output: Contribution to journalArticle

42 Scopus citations

Abstract

Vanadium complexes have been used extensively to catalyze olefin and alcohol oxidation. However, their application in C-H oxidation has not been well-studied. We report herein that commercially available Cp 2VCl2 catalyzes benzylic C-H oxidation selectively and effectively, giving no aromatic oxidation products.

Original languageEnglish (US)
Pages (from-to)2240-2245
Number of pages6
JournalChemical Science
Volume3
Issue number7
DOIs
StatePublished - Jul 2012

ASJC Scopus subject areas

  • Chemistry(all)

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