A mild light-induced cleavage of the S-O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes

Maxim Ratushnyy, Monika Kamenova, Vladimir Gevorgyan

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

A new mode of S-O bond activation has been discovered, which constitutes novel reactivity of easily available and bench-stable arylsulfonate phenol esters. This protocol enables access to putative sulfonyl radical intermediates, which enable straightforward access to valuable vinyl sulfones.

Original languageEnglish (US)
Pages (from-to)7193-7197
Number of pages5
JournalChemical Science
Volume9
Issue number36
DOIs
Publication statusPublished - Jan 1 2018
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)

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