Additions and Corrections: (Copper(I)-Promoted Thiophenoxide Ionization in Solution. A Simple Synthesis of Vinyl Phenyl Sulfides (1975) 40(6) (812–813) (10.1021/jo00894a038))

Theodore Cohen, Glen Herman, J. R. Falck, Albert J. Mura

Research output: Contribution to journalComment/debate

Abstract

Oxidation of Schiff bases formed by the reaction of chiral (R)-(+)-α-phenylethylamine and carbonyl compound using m-chloroperbenzoic acid gives rise to the formation of nonracemic diastereomeric 3,3-disubstituted oxaziridines in a high optical yield. Oxidation of (E)-(R)-(—)-N-benzylidene-α-phenylethylamine yields a mixture of all four possible nonracemic diastereomers with predominance of E products.

Original languageEnglish (US)
Number of pages1
JournalJournal of Organic Chemistry
Volume40
Issue number25
DOIs
StatePublished - Dec 1 1975

ASJC Scopus subject areas

  • Organic Chemistry

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