B(C6F5)3-catalyzed allylation of propargyl acetates with allylsilanes

Todd Schwier; Michael Rubin; Vladimir Gevorgyan

doi:10.1021/ol0494055

B(C₆F₅)₃-catalyzed allylation of propargyl acetates with allylsilanes

Todd Schwier, Michael Rubin, Vladimir Gevorgyan

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82 Scopus citations

Abstract

Equation presented. An efficient method for the B(C₆F ₅)₃-catalyzed allylation of secondary propargylic alcohol derivatives with allylsilanes has been developed. This method allows for the facile synthesis of a variety of 1,5-enynes in good to high yields with a number of functionalities, such as nitro, chloro, ester, and boronic ester, being tolerated under the reaction conditions.

Original language	English (US)
Pages (from-to)	1999-2001
Number of pages	3
Journal	Organic Letters
Volume	6
Issue number	12
DOIs	https://doi.org/10.1021/ol0494055
State	Published - Jun 10 2004
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0494055

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title = "B(C6F5)3-catalyzed allylation of propargyl acetates with allylsilanes",

abstract = "Equation presented. An efficient method for the B(C6F 5)3-catalyzed allylation of secondary propargylic alcohol derivatives with allylsilanes has been developed. This method allows for the facile synthesis of a variety of 1,5-enynes in good to high yields with a number of functionalities, such as nitro, chloro, ester, and boronic ester, being tolerated under the reaction conditions.",

author = "Todd Schwier and Michael Rubin and Vladimir Gevorgyan",

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T1 - B(C6F5)3-catalyzed allylation of propargyl acetates with allylsilanes

AU - Schwier, Todd

AU - Rubin, Michael

AU - Gevorgyan, Vladimir

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Y1 - 2004/6/10

N2 - Equation presented. An efficient method for the B(C6F 5)3-catalyzed allylation of secondary propargylic alcohol derivatives with allylsilanes has been developed. This method allows for the facile synthesis of a variety of 1,5-enynes in good to high yields with a number of functionalities, such as nitro, chloro, ester, and boronic ester, being tolerated under the reaction conditions.

AB - Equation presented. An efficient method for the B(C6F 5)3-catalyzed allylation of secondary propargylic alcohol derivatives with allylsilanes has been developed. This method allows for the facile synthesis of a variety of 1,5-enynes in good to high yields with a number of functionalities, such as nitro, chloro, ester, and boronic ester, being tolerated under the reaction conditions.

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ER -

B(C₆F₅)₃-catalyzed allylation of propargyl acetates with allylsilanes

Abstract

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