B(C6F5)3-catalyzed allylation of propargyl acetates with allylsilanes

Todd Schwier, Michael Rubin, Vladimir Gevorgyan

Research output: Contribution to journalArticle

67 Scopus citations

Abstract

Equation presented. An efficient method for the B(C6F 5)3-catalyzed allylation of secondary propargylic alcohol derivatives with allylsilanes has been developed. This method allows for the facile synthesis of a variety of 1,5-enynes in good to high yields with a number of functionalities, such as nitro, chloro, ester, and boronic ester, being tolerated under the reaction conditions.

Original languageEnglish (US)
Pages (from-to)1999-2001
Number of pages3
JournalOrganic Letters
Volume6
Issue number12
DOIs
StatePublished - Jun 10 2004
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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