B(C6F5)3-catalyzed allylation of secondary benzyl acetates with allylsilanes

Michael Rubin, Vladimir Gevorgyan

Research output: Contribution to journalArticle

114 Scopus citations

Abstract

(Equation presented) A highly effective protocol for allylation of secondary benzylic alcohol derivatives with allylsilanes in the presence of catalytic amounts of B(C6F5)3 has been developed. Some additional functionalities, such as bromo, acetoxy, and primary benzyloxy groups, were tolerated under these conditions.

Original languageEnglish (US)
Pages (from-to)2705-2707
Number of pages3
JournalOrganic Letters
Volume3
Issue number17
DOIs
StatePublished - Aug 23 2001
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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