B(C6F5)3-catalyzed allylation of secondary benzyl acetates with allylsilanes

Michael Rubin; Vladimir Gevorgyan

doi:10.1021/ol016300i

B(C₆F₅)₃-catalyzed allylation of secondary benzyl acetates with allylsilanes

Michael Rubin, Vladimir Gevorgyan

Research output: Contribution to journal › Article › peer-review

125 Scopus citations

Abstract

(Equation presented) A highly effective protocol for allylation of secondary benzylic alcohol derivatives with allylsilanes in the presence of catalytic amounts of B(C₆F₅)₃ has been developed. Some additional functionalities, such as bromo, acetoxy, and primary benzyloxy groups, were tolerated under these conditions.

Original language	English (US)
Pages (from-to)	2705-2707
Number of pages	3
Journal	Organic Letters
Volume	3
Issue number	17
DOIs	https://doi.org/10.1021/ol016300i
State	Published - Aug 23 2001
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol016300i

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title = "B(C6F5)3-catalyzed allylation of secondary benzyl acetates with allylsilanes",

abstract = "(Equation presented) A highly effective protocol for allylation of secondary benzylic alcohol derivatives with allylsilanes in the presence of catalytic amounts of B(C6F5)3 has been developed. Some additional functionalities, such as bromo, acetoxy, and primary benzyloxy groups, were tolerated under these conditions.",

author = "Michael Rubin and Vladimir Gevorgyan",

year = "2001",

month = aug,

day = "23",

doi = "10.1021/ol016300i",

language = "English (US)",

volume = "3",

pages = "2705--2707",

journal = "Organic Letters",

issn = "1523-7060",

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T1 - B(C6F5)3-catalyzed allylation of secondary benzyl acetates with allylsilanes

AU - Rubin, Michael

AU - Gevorgyan, Vladimir

PY - 2001/8/23

Y1 - 2001/8/23

N2 - (Equation presented) A highly effective protocol for allylation of secondary benzylic alcohol derivatives with allylsilanes in the presence of catalytic amounts of B(C6F5)3 has been developed. Some additional functionalities, such as bromo, acetoxy, and primary benzyloxy groups, were tolerated under these conditions.

AB - (Equation presented) A highly effective protocol for allylation of secondary benzylic alcohol derivatives with allylsilanes in the presence of catalytic amounts of B(C6F5)3 has been developed. Some additional functionalities, such as bromo, acetoxy, and primary benzyloxy groups, were tolerated under these conditions.

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DO - 10.1021/ol016300i

M3 - Article

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AN - SCOPUS:0008890383

SN - 1523-7060

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SP - 2705

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JO - Organic Letters

JF - Organic Letters

IS - 17

ER -

B(C₆F₅)₃-catalyzed allylation of secondary benzyl acetates with allylsilanes

Abstract

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