Bu4NF-BF3·Et2O as a new reagent for the selective deprotection of the enol ethers of γ-alkoxyallylstananes

Vladimir Gevorgyan; Yoshinori Yamamoto

doi:10.1039/C39940000059

Bu₄NF-BF₃·Et₂O as a new reagent for the selective deprotection of the enol ethers of γ-alkoxyallylstananes

Vladimir Gevorgyan, Yoshinori Yamamoto

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The combination of Bu₄NF-BF₃·OEt₂ deprotects selectively the enol ether protecting group of γ-alkoxy- and benzyloxy-allytributylstannanes, without destannylating the tributylstannyl group, affording the corresponding γ-tributylstannyl aldehyde in high yield.

Original language	English (US)
Pages (from-to)	59-60
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/C39940000059
State	Published - Dec 1 1994
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Bu4NF-BF3·Et2O as a new reagent for the selective deprotection of the enol ethers of γ-alkoxyallylstananes",

abstract = "The combination of Bu4NF-BF3·OEt2 deprotects selectively the enol ether protecting group of γ-alkoxy- and benzyloxy-allytributylstannanes, without destannylating the tributylstannyl group, affording the corresponding γ-tributylstannyl aldehyde in high yield.",

author = "Vladimir Gevorgyan and Yoshinori Yamamoto",

year = "1994",

month = dec,

day = "1",

doi = "10.1039/C39940000059",

language = "English (US)",

pages = "59--60",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "1",

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T1 - Bu4NF-BF3·Et2O as a new reagent for the selective deprotection of the enol ethers of γ-alkoxyallylstananes

AU - Gevorgyan, Vladimir

AU - Yamamoto, Yoshinori

PY - 1994/12/1

Y1 - 1994/12/1

N2 - The combination of Bu4NF-BF3·OEt2 deprotects selectively the enol ether protecting group of γ-alkoxy- and benzyloxy-allytributylstannanes, without destannylating the tributylstannyl group, affording the corresponding γ-tributylstannyl aldehyde in high yield.

AB - The combination of Bu4NF-BF3·OEt2 deprotects selectively the enol ether protecting group of γ-alkoxy- and benzyloxy-allytributylstannanes, without destannylating the tributylstannyl group, affording the corresponding γ-tributylstannyl aldehyde in high yield.

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Bu₄NF-BF₃·Et₂O as a new reagent for the selective deprotection of the enol ethers of γ-alkoxyallylstananes

Abstract

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