Catalytic Enantioselective Hydrostannation of Cyclopropenes

Marina Rubina, Michael Rubin, Vladimir Gevorgyan

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72 Scopus citations

Abstract

The first examples of catalytic enantioselective hydrostannation of the C=C double bond of cyclopropenes has been demonstrated. This method allows for the efficient synthesis of 2,2-disubstituted cyclopropylstannanes with high degrees of diastereo- and enantioselectivity. The facial selectivity of this reaction is entirely controlled by steric factors. A variety of functional groups at C-3 of the cyclopropenes were tolerated.

Original languageEnglish (US)
Pages (from-to)3688-3689
Number of pages2
JournalJournal of the American Chemical Society
Volume126
Issue number12
DOIs
StatePublished - Mar 31 2004

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ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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