Chromium-carbyne complexes: Intermediates for organic synthesis

Romain Bejot, Anyu He, J R Falck, Charles Mioskowski

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

(Chemical Equation Presented) On the same route: Chromium-carbyne complexes are readily prepared by treatment of 1,1,1-trichloromethyl reagents with chromium(II) chloride. They serve as intermediates in the selective formation of a wide variety of products, such as alkynes, alkenes, β-hydroxy ketones, aldehydes, allylic alcohols, and allenes (see scheme, E = electrophile).

Original languageEnglish (US)
Pages (from-to)1719-1722
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number10
DOIs
StatePublished - 2007

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Chromium
Alkynes
Alkenes
Ketones
Aldehydes
Olefins
Chlorides
Alcohols
barban
propadiene
allyl alcohol

Keywords

  • Carbenes
  • Carbynes
  • Chromium
  • Isotopic labeling
  • Rearrangements

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Chromium-carbyne complexes : Intermediates for organic synthesis. / Bejot, Romain; He, Anyu; Falck, J R; Mioskowski, Charles.

In: Angewandte Chemie - International Edition, Vol. 46, No. 10, 2007, p. 1719-1722.

Research output: Contribution to journalArticle

Bejot, Romain ; He, Anyu ; Falck, J R ; Mioskowski, Charles. / Chromium-carbyne complexes : Intermediates for organic synthesis. In: Angewandte Chemie - International Edition. 2007 ; Vol. 46, No. 10. pp. 1719-1722.
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