Chromium-carbyne complexes: Intermediates for organic synthesis

Romain Bejot; Anyu He; J R Falck; Charles Mioskowski

doi:10.1002/anie.200604015

Chromium-carbyne complexes: Intermediates for organic synthesis

Romain Bejot, Anyu He, J R Falck, Charles Mioskowski

Biochemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

(Chemical Equation Presented) On the same route: Chromium-carbyne complexes are readily prepared by treatment of 1,1,1-trichloromethyl reagents with chromium(II) chloride. They serve as intermediates in the selective formation of a wide variety of products, such as alkynes, alkenes, β-hydroxy ketones, aldehydes, allylic alcohols, and allenes (see scheme, E = electrophile).

Original language	English (US)
Pages (from-to)	1719-1722
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	10
DOIs	https://doi.org/10.1002/anie.200604015
State	Published - 2007

Keywords

Carbenes
Carbynes
Chromium
Isotopic labeling
Rearrangements

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200604015

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abstract = "(Chemical Equation Presented) On the same route: Chromium-carbyne complexes are readily prepared by treatment of 1,1,1-trichloromethyl reagents with chromium(II) chloride. They serve as intermediates in the selective formation of a wide variety of products, such as alkynes, alkenes, β-hydroxy ketones, aldehydes, allylic alcohols, and allenes (see scheme, E = electrophile).",

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author = "Romain Bejot and Anyu He and Falck, {J R} and Charles Mioskowski",

year = "2007",

doi = "10.1002/anie.200604015",

language = "English (US)",

volume = "46",

pages = "1719--1722",

journal = "Angewandte Chemie - International Edition",

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T1 - Chromium-carbyne complexes

T2 - Intermediates for organic synthesis

AU - Bejot, Romain

AU - He, Anyu

AU - Falck, J R

AU - Mioskowski, Charles

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) On the same route: Chromium-carbyne complexes are readily prepared by treatment of 1,1,1-trichloromethyl reagents with chromium(II) chloride. They serve as intermediates in the selective formation of a wide variety of products, such as alkynes, alkenes, β-hydroxy ketones, aldehydes, allylic alcohols, and allenes (see scheme, E = electrophile).

AB - (Chemical Equation Presented) On the same route: Chromium-carbyne complexes are readily prepared by treatment of 1,1,1-trichloromethyl reagents with chromium(II) chloride. They serve as intermediates in the selective formation of a wide variety of products, such as alkynes, alkenes, β-hydroxy ketones, aldehydes, allylic alcohols, and allenes (see scheme, E = electrophile).

KW - Carbenes

KW - Carbynes

KW - Chromium

KW - Isotopic labeling

KW - Rearrangements

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 10

ER -

Chromium-carbyne complexes: Intermediates for organic synthesis

Abstract

Keywords

ASJC Scopus subject areas

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