Conversions of [2-(4,5-dihydrofuryl)]-silanes and -germanes under catalytic hydrogenation conditions

E. Lukevics; V. N. Gevorgyan; Y. S. Goldberg; M. V. Shymanska

doi:10.1016/0022-328X(85)87465-9

Conversions of [2-(4,5-dihydrofuryl)]-silanes and -germanes under catalytic hydrogenation conditions

E. Lukevics, V. N. Gevorgyan, Y. S. Goldberg, M. V. Shymanska

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12 Scopus citations

Abstract

(2-Tetrahydrofuryl)-silanes and -germanes were obtained in high yield by the heterogeneous liquid-phase hydrogenation of [2-(4,5-dihydrofuryl)]trimethylsilane (I), bis[2-(4,5-dihydrofuryl)]dimethylsilane (II) and [2-(4,5-dihydrofuryl)]trimethylgermane with a Pd/Al₂O₃ catalyst. The dihydrofurylsilanes I and II were found to undergo disproportionation and dehydrogenation, the latter being involved in both intra- and inter-molecular disproportionation.

Original language	English (US)
Pages (from-to)	163-171
Number of pages	9
Journal	Journal of Organometallic Chemistry
Volume	294
Issue number	2
DOIs	https://doi.org/10.1016/0022-328X(85)87465-9
State	Published - Oct 15 1985
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Conversions of [2-(4,5-dihydrofuryl)]-silanes and -germanes under catalytic hydrogenation conditions",

abstract = "(2-Tetrahydrofuryl)-silanes and -germanes were obtained in high yield by the heterogeneous liquid-phase hydrogenation of [2-(4,5-dihydrofuryl)]trimethylsilane (I), bis[2-(4,5-dihydrofuryl)]dimethylsilane (II) and [2-(4,5-dihydrofuryl)]trimethylgermane with a Pd/Al2O3 catalyst. The dihydrofurylsilanes I and II were found to undergo disproportionation and dehydrogenation, the latter being involved in both intra- and inter-molecular disproportionation.",

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T1 - Conversions of [2-(4,5-dihydrofuryl)]-silanes and -germanes under catalytic hydrogenation conditions

AU - Lukevics, E.

AU - Gevorgyan, V. N.

AU - Goldberg, Y. S.

AU - Shymanska, M. V.

PY - 1985/10/15

Y1 - 1985/10/15

N2 - (2-Tetrahydrofuryl)-silanes and -germanes were obtained in high yield by the heterogeneous liquid-phase hydrogenation of [2-(4,5-dihydrofuryl)]trimethylsilane (I), bis[2-(4,5-dihydrofuryl)]dimethylsilane (II) and [2-(4,5-dihydrofuryl)]trimethylgermane with a Pd/Al2O3 catalyst. The dihydrofurylsilanes I and II were found to undergo disproportionation and dehydrogenation, the latter being involved in both intra- and inter-molecular disproportionation.

AB - (2-Tetrahydrofuryl)-silanes and -germanes were obtained in high yield by the heterogeneous liquid-phase hydrogenation of [2-(4,5-dihydrofuryl)]trimethylsilane (I), bis[2-(4,5-dihydrofuryl)]dimethylsilane (II) and [2-(4,5-dihydrofuryl)]trimethylgermane with a Pd/Al2O3 catalyst. The dihydrofurylsilanes I and II were found to undergo disproportionation and dehydrogenation, the latter being involved in both intra- and inter-molecular disproportionation.

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Conversions of [2-(4,5-dihydrofuryl)]-silanes and -germanes under catalytic hydrogenation conditions

Abstract

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