Conversions of [2-(4,5-dihydrofuryl)]-silanes and -germanes under catalytic hydrogenation conditions

E. Lukevics, V. N. Gevorgyan, Y. S. Goldberg, M. V. Shymanska

Research output: Contribution to journalArticle

10 Scopus citations

Abstract

(2-Tetrahydrofuryl)-silanes and -germanes were obtained in high yield by the heterogeneous liquid-phase hydrogenation of [2-(4,5-dihydrofuryl)]trimethylsilane (I), bis[2-(4,5-dihydrofuryl)]dimethylsilane (II) and [2-(4,5-dihydrofuryl)]trimethylgermane with a Pd/Al2O3 catalyst. The dihydrofurylsilanes I and II were found to undergo disproportionation and dehydrogenation, the latter being involved in both intra- and inter-molecular disproportionation.

Original languageEnglish (US)
Pages (from-to)163-171
Number of pages9
JournalJournal of Organometallic Chemistry
Volume294
Issue number2
DOIs
StatePublished - Oct 15 1985
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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