Corrigendum to: Nickel-Catalyzed Barton Decarboxylation and Giese Reactions: A Practical Take on Classic Transforms (Angewandte Chemie International Edition, (2017), 56, 1, (260-265), 10.1002/anie.201609662)

Tian Qin, Lara R. Malins, Jacob T. Edwards, Rohan R. Merchant, Alexander J.E. Novak, Jacob Z. Zhong, Riley B. Mills, Ming Yan, Changxia Yuan, Martin D. Eastgate, Phil S. Baran

Research output: Contribution to journalComment/debate

Abstract

In this Communication, compound 41 was assigned as the exo stereochemistry upon Giese reaction of a pyrroloindoline redox-active ester with benzyl acrylate. On subsequent NOESY studies of 41, a correlation between H2 and H5 was observed. Therefore, the authors have concluded that the stereochemistry of the product was misassigned and should be endo instead. Prof. David Crich and co-workers have previously reported the endo quench of the radical from pyrroloindoline acid. The authors would like to acknowledge Prof. David Crich for identifying the misassignment. Additional references and NOESY spectrum of compound 41 have been attached to support this assignment. None of the conclusions in the Communication are affected.

Original languageEnglish (US)
Number of pages1
JournalAngewandte Chemie - International Edition
Volume58
Issue number7
DOIs
StatePublished - Feb 11 2019

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Stereochemistry
Nickel
Mathematical transformations
Communication
Esters
Acids
corrigendum
Decarboxylation
Oxidation-Reduction
acrylic acid

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Corrigendum to : Nickel-Catalyzed Barton Decarboxylation and Giese Reactions: A Practical Take on Classic Transforms (Angewandte Chemie International Edition, (2017), 56, 1, (260-265), 10.1002/anie.201609662). / Qin, Tian; Malins, Lara R.; Edwards, Jacob T.; Merchant, Rohan R.; Novak, Alexander J.E.; Zhong, Jacob Z.; Mills, Riley B.; Yan, Ming; Yuan, Changxia; Eastgate, Martin D.; Baran, Phil S.

In: Angewandte Chemie - International Edition, Vol. 58, No. 7, 11.02.2019.

Research output: Contribution to journalComment/debate

Qin, Tian ; Malins, Lara R. ; Edwards, Jacob T. ; Merchant, Rohan R. ; Novak, Alexander J.E. ; Zhong, Jacob Z. ; Mills, Riley B. ; Yan, Ming ; Yuan, Changxia ; Eastgate, Martin D. ; Baran, Phil S. / Corrigendum to : Nickel-Catalyzed Barton Decarboxylation and Giese Reactions: A Practical Take on Classic Transforms (Angewandte Chemie International Edition, (2017), 56, 1, (260-265), 10.1002/anie.201609662). In: Angewandte Chemie - International Edition. 2019 ; Vol. 58, No. 7.
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abstract = "In this Communication, compound 41 was assigned as the exo stereochemistry upon Giese reaction of a pyrroloindoline redox-active ester with benzyl acrylate. On subsequent NOESY studies of 41, a correlation between H2 and H5 was observed. Therefore, the authors have concluded that the stereochemistry of the product was misassigned and should be endo instead. Prof. David Crich and co-workers have previously reported the endo quench of the radical from pyrroloindoline acid. The authors would like to acknowledge Prof. David Crich for identifying the misassignment. Additional references and NOESY spectrum of compound 41 have been attached to support this assignment. None of the conclusions in the Communication are affected.",
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AU - Merchant, Rohan R.

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