Crystal and molecular structure of tetraethyl-ammonium bis (stilbene 1,2-dithiolato) nickelate(III)

A. Rajalakshmi, Akella Radha, M. Seshasayee, P. Kuppusamy, P. T. Manoharan

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The crystals of the title compound are orthorhombic, space group Pca2l with the following parameters: a = 16.387(4), b = 7.507(2), c = 28.612(8) A°, V= 6343.8 A°3, Z = 4, Dx = 1.35 g cm-3, ℳ(MoK) = 0.753 mm-1, Final R = 0.11, Rw = 0.12 with 1.00/[σ2(Fo) + 0.0005 |F0|2] for 1073 unique redections [I> 3σ(I)]. The nickel atom has an approximate square planar configuration. The nitrogen atom of the cation exhibits a tetrahedral configuration. The anions are arranged along the a-axis at Z = 0.25 and 0.75 with the Nickel atoms nearly collinear.

Original languageEnglish (US)
Pages (from-to)159-164
Number of pages6
JournalZeitschrift fur Kristallographie - New Crystal Structures
Volume187
Issue number1-2
DOIs
StatePublished - 1989

Keywords

  • 2-dithiolene complex
  • Crystal structure
  • One-dimensional complex
  • Stilbene 1

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Inorganic Chemistry

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