@article{0a3f10b8a88e4dd2a223abcc91bb6d4e,
title = "Cu-Catalyzed Decarboxylative Borylation",
abstract = "A simple method for the conversion of carboxylic acids to boronic esters via redox-active esters (RAEs) is reported using copper catalysis. The scope of this transformation is broad, and compared with the known protocols available, it represents the most inexpensive, rapid, and operationally simple option. In addition to a full exploration of the scope, a kinetic study was performed to elucidate substrate and reagent concentration dependences.",
keywords = "copper catalysis, decarboxylative borylation, kinetic studies, practical protocol, redox-active esters",
author = "Jie Wang and Ming Shang and Helena Lundberg and Feu, {Karla S.} and Hecker, {Scott J.} and Tian Qin and Blackmond, {Donna G.} and Baran, {Phil S.}",
note = "Funding Information: Financial support for this work was provided by NIH (grant number GM-118176). The Swedish Research Council, The Foundation Blanceflor Boncompagni-Ludovisi ne{\'e} Bildt, Stiftelsen Olle Engkvist Byggmastare{\",} and The Hans Werthe{\'n} Fund Scholarship supported research fellowships to H.L; Zhejiang Yuanhong Medicine Technology Co. Ltd. supported fellowships to M.S.; Sa{\~o} Paulo Research Foundation (FAPESP, 2017/08128-7) supported fellowships to K.S.F. We thank D.-H. Huang and L. Pasternack (The Scripps Research Institute) for assistance with nuclear magnetic resonance spectroscopy. We are grateful to Dr. Jason S. Chen (The Scripps Research Institute) for assistance with the kinetic studies and Michael Collins (Pfizer) for providing atorvastatin sample. We also thank A.L. Rheingold, C.E. Moore and M. Gembicky (University of California, San Diego) for X-ray crystallographic analysis. Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",
year = "2018",
month = oct,
day = "5",
doi = "10.1021/acscatal.8b02928",
language = "English (US)",
volume = "8",
pages = "9537--9542",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "10",
}