Cu-catalyzed transannulation reaction of pyridotriazoles: General access to fused polycyclic indolizines

Yi Shi; Vladimir Gevorgyan

doi:10.1039/c5cc07598j

Cu-catalyzed transannulation reaction of pyridotriazoles: General access to fused polycyclic indolizines

Yi Shi, Vladimir Gevorgyan

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

An efficient intramolecular transannulation reaction of pyridotriazoles using internal alkynes en route to various fused polycyclic indolizines has been developed. For the first time it is shown that in addition to the well-established Rh- or Cu-catalyzed carbene mechanism, the transannulation reaction could also follow a Lewis acid-mediated electrophilic pathway.

Original language	English (US)
Pages (from-to)	17166-17169
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	96
DOIs	https://doi.org/10.1039/c5cc07598j
State	Published - 2015
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c5cc07598j

Cite this

@article{a05f07a3ef2345278f818de3026e6922,

title = "Cu-catalyzed transannulation reaction of pyridotriazoles: General access to fused polycyclic indolizines",

abstract = "An efficient intramolecular transannulation reaction of pyridotriazoles using internal alkynes en route to various fused polycyclic indolizines has been developed. For the first time it is shown that in addition to the well-established Rh- or Cu-catalyzed carbene mechanism, the transannulation reaction could also follow a Lewis acid-mediated electrophilic pathway.",

author = "Yi Shi and Vladimir Gevorgyan",

note = "Publisher Copyright: {\textcopyright} 2015 The Royal Society of Chemistry.",

year = "2015",

doi = "10.1039/c5cc07598j",

language = "English (US)",

volume = "51",

pages = "17166--17169",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "96",

}

TY - JOUR

T1 - Cu-catalyzed transannulation reaction of pyridotriazoles

T2 - General access to fused polycyclic indolizines

AU - Shi, Yi

AU - Gevorgyan, Vladimir

PY - 2015

Y1 - 2015

N2 - An efficient intramolecular transannulation reaction of pyridotriazoles using internal alkynes en route to various fused polycyclic indolizines has been developed. For the first time it is shown that in addition to the well-established Rh- or Cu-catalyzed carbene mechanism, the transannulation reaction could also follow a Lewis acid-mediated electrophilic pathway.

AB - An efficient intramolecular transannulation reaction of pyridotriazoles using internal alkynes en route to various fused polycyclic indolizines has been developed. For the first time it is shown that in addition to the well-established Rh- or Cu-catalyzed carbene mechanism, the transannulation reaction could also follow a Lewis acid-mediated electrophilic pathway.

UR - http://www.scopus.com/inward/record.url?scp=84948131309&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84948131309&partnerID=8YFLogxK

U2 - 10.1039/c5cc07598j

DO - 10.1039/c5cc07598j

M3 - Article

C2 - 26456098

AN - SCOPUS:84948131309

SN - 1359-7345

VL - 51

SP - 17166

EP - 17169

JO - Chemical Communications

JF - Chemical Communications

IS - 96

ER -

Cu-catalyzed transannulation reaction of pyridotriazoles: General access to fused polycyclic indolizines

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this