Cu-catalyzed transannulation reaction of pyridotriazoles: General access to fused polycyclic indolizines

Research output: Contribution to journalArticle

39 Scopus citations

Abstract

An efficient intramolecular transannulation reaction of pyridotriazoles using internal alkynes en route to various fused polycyclic indolizines has been developed. For the first time it is shown that in addition to the well-established Rh- or Cu-catalyzed carbene mechanism, the transannulation reaction could also follow a Lewis acid-mediated electrophilic pathway.

Original languageEnglish (US)
Pages (from-to)17166-17169
Number of pages4
JournalChemical Communications
Volume51
Issue number96
DOIs
StatePublished - Jan 1 2015
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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