Cu(II)-Mediated N-H and N-Alkyl Aryl Amination and Olefin Aziridination

Sailu Munnuri; Raghunath Reddy Anugu; John R. Falck

doi:10.1021/acs.orglett.9b00586

Cu(II)-Mediated N-H and N-Alkyl Aryl Amination and Olefin Aziridination

Sailu Munnuri, Raghunath Reddy Anugu, John R. Falck

Biochemistry

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Cu(II)-mediated direct NH ₂ and NH alkyl aryl aminations and olefin aziridinations are described. These room-temperature, one-pot, environmentally friendly procedures replace costly Rh ₂ catalysts and, in some instances, display important differences with comparable Rh ₂ - and Fe-supported reactions.

Original language	English (US)
Pages (from-to)	1926-1929
Number of pages	4
Journal	Organic Letters
Volume	21
Issue number	6
DOIs	https://doi.org/10.1021/acs.orglett.9b00586
State	Published - Mar 15 2019

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Cu(II)-Mediated N-H and N-Alkyl Aryl Amination and Olefin Aziridination",

abstract = " Cu(II)-mediated direct NH 2 and NH alkyl aryl aminations and olefin aziridinations are described. These room-temperature, one-pot, environmentally friendly procedures replace costly Rh 2 catalysts and, in some instances, display important differences with comparable Rh 2 - and Fe-supported reactions. ",

author = "Sailu Munnuri and Anugu, {Raghunath Reddy} and Falck, {John R.}",

note = "Funding Information: Financial support from the Robert A. Welch Foundation (No. I-0011), the Dr. Ralph and Marian Falk Medical Research Trust Bank of America, N.A., Trustee, and NIH (No. R01HL139793) is acknowledged. Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

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doi = "10.1021/acs.orglett.9b00586",

language = "English (US)",

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T1 - Cu(II)-Mediated N-H and N-Alkyl Aryl Amination and Olefin Aziridination

AU - Munnuri, Sailu

AU - Anugu, Raghunath Reddy

AU - Falck, John R.

N1 - Funding Information: Financial support from the Robert A. Welch Foundation (No. I-0011), the Dr. Ralph and Marian Falk Medical Research Trust Bank of America, N.A., Trustee, and NIH (No. R01HL139793) is acknowledged. Publisher Copyright: © 2019 American Chemical Society.

PY - 2019/3/15

Y1 - 2019/3/15

N2 - Cu(II)-mediated direct NH 2 and NH alkyl aryl aminations and olefin aziridinations are described. These room-temperature, one-pot, environmentally friendly procedures replace costly Rh 2 catalysts and, in some instances, display important differences with comparable Rh 2 - and Fe-supported reactions.

AB - Cu(II)-mediated direct NH 2 and NH alkyl aryl aminations and olefin aziridinations are described. These room-temperature, one-pot, environmentally friendly procedures replace costly Rh 2 catalysts and, in some instances, display important differences with comparable Rh 2 - and Fe-supported reactions.

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JO - Organic Letters

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Cu(II)-Mediated N-H and N-Alkyl Aryl Amination and Olefin Aziridination

Abstract

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