Abstract
We present (3+2)- and (4+2)-cycloadditions of donor–acceptor (D–A) cyclopropanes and cyclobutanes with N-sulfinylamines and a sulfur diimide, along with a one-pot, two-step strategy for the formal insertion of HNSO2 into D–A cyclopropanes. These are rare examples of cycloadditions with D–A cyclopropanes and cyclobutanes whereby the 2π component consists of two different heteroatoms, thus leading to five- and six-membered rings containing adjacent heteroatoms.
Original language | English (US) |
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Pages (from-to) | 25825-25831 |
Number of pages | 7 |
Journal | Angewandte Chemie - International Edition |
Volume | 60 |
Issue number | 49 |
DOIs | |
State | Published - Dec 1 2021 |
Keywords
- cycloadditions
- cyclopropanes
- donor–acceptor systems
- sulfinylamines
- sulfur diimide
ASJC Scopus subject areas
- Catalysis
- General Chemistry