Distribution potential in small liquid-liquid systems

Vladislav S. Markin, Alexander G. Volkov

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

For the first time, the distribution potential at the oil/water interface is calculated for a small system with a small volume of one of the phases. The analytical solution for a nanoheterogeneous system is obtained without assuming the electroneutrality in each phase. If the thickness of an oil droplet is comparable with the Debye screening length and the distribution potential exceeds kT/e 0, then the solution can be found numerically.

Original languageEnglish (US)
Pages (from-to)13807-13812
Number of pages6
JournalJournal of Physical Chemistry B
Volume108
Issue number36
DOIs
StatePublished - Sep 9 2004

Fingerprint

Oils
oils
Liquids
liquids
Screening
screening
Water
water

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Distribution potential in small liquid-liquid systems. / Markin, Vladislav S.; Volkov, Alexander G.

In: Journal of Physical Chemistry B, Vol. 108, No. 36, 09.09.2004, p. 13807-13812.

Research output: Contribution to journalArticle

Markin, Vladislav S. ; Volkov, Alexander G. / Distribution potential in small liquid-liquid systems. In: Journal of Physical Chemistry B. 2004 ; Vol. 108, No. 36. pp. 13807-13812.
@article{01e4465a84fa4a31b6ad4fee214d049f,
title = "Distribution potential in small liquid-liquid systems",
abstract = "For the first time, the distribution potential at the oil/water interface is calculated for a small system with a small volume of one of the phases. The analytical solution for a nanoheterogeneous system is obtained without assuming the electroneutrality in each phase. If the thickness of an oil droplet is comparable with the Debye screening length and the distribution potential exceeds kT/e 0, then the solution can be found numerically.",
author = "Markin, {Vladislav S.} and Volkov, {Alexander G.}",
year = "2004",
month = "9",
day = "9",
doi = "10.1021/jp0485385",
language = "English (US)",
volume = "108",
pages = "13807--13812",
journal = "Journal of Physical Chemistry B Materials",
issn = "1520-6106",
publisher = "American Chemical Society",
number = "36",

}

TY - JOUR

T1 - Distribution potential in small liquid-liquid systems

AU - Markin, Vladislav S.

AU - Volkov, Alexander G.

PY - 2004/9/9

Y1 - 2004/9/9

N2 - For the first time, the distribution potential at the oil/water interface is calculated for a small system with a small volume of one of the phases. The analytical solution for a nanoheterogeneous system is obtained without assuming the electroneutrality in each phase. If the thickness of an oil droplet is comparable with the Debye screening length and the distribution potential exceeds kT/e 0, then the solution can be found numerically.

AB - For the first time, the distribution potential at the oil/water interface is calculated for a small system with a small volume of one of the phases. The analytical solution for a nanoheterogeneous system is obtained without assuming the electroneutrality in each phase. If the thickness of an oil droplet is comparable with the Debye screening length and the distribution potential exceeds kT/e 0, then the solution can be found numerically.

UR - http://www.scopus.com/inward/record.url?scp=4544227091&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=4544227091&partnerID=8YFLogxK

U2 - 10.1021/jp0485385

DO - 10.1021/jp0485385

M3 - Article

AN - SCOPUS:4544227091

VL - 108

SP - 13807

EP - 13812

JO - Journal of Physical Chemistry B Materials

JF - Journal of Physical Chemistry B Materials

SN - 1520-6106

IS - 36

ER -