Elusive metal-free primary amination of arylboronic acids: Synthetic studies and mechanism by density functional theory

Engineering & Materials Science

• Amination 100%
• Aniline 82%
• Density functional theory 78%
• Acids 47%
• Energy barriers 40%
• Transition metals 38%
• Metals 33%
• Free energy 31%
• Amines 31%

Medicine & Life Sciences

• Aniline Compounds 95%
• Density Functional Theory 92%
• Amination 87%
• Metals 45%
• Acids 39%
• Amines 27%

Chemical Compounds

• Aniline 44%
• Primary Arylamine 44%
• Density Functional Theory 32%
• Neutral Condition 29%
• Aromatic Amine 27%
• Nitro Group 27%
• Alkaline Condition 25%
• Energy Barrier 25%
• Gibbs Free Energy 19%
• Acid 18%
• Chemical Transformation 16%
• Reaction Yield 10%