Generation and cycloaddition of semi-stabilized 2-azaallyllithiums viaelectrocyclic ring-opening or cycloreversion reactions

William H. Pearson, Michael A. Walters, Michael K. Rosen, William G. Harter

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

Semi-stabilized 2-azaallyl anions, i.e., those bearing aryl groups, have been generated by either the electrocyclic ring-opening of N-lithioaziridines or the 1,3-anionic cycloreversion of N-lithioimidazolidines.

Original languageEnglish (US)
Pages (from-to)91-111
Number of pages21
JournalArkivoc
Volume2002
Issue number8
StatePublished - Dec 1 2002

Keywords

  • 2-azaallylanion
  • 2-azaallyllithium
  • Aziridine
  • Cycloreversion
  • Electrocyclic ring-opening
  • Imidazolidine

ASJC Scopus subject areas

  • Organic Chemistry

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