Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol esters via rearrangement of Fischer chromium chloro-carbenes using microwave irradiation

Dhurke Kashinath, Charles Mioskowski, J R Falck, Mohan Goli, Stéphane Meunier, Rachid Baati, Alain Wagner

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

Functionalized (Z,E)-1-halo-1,3-dienol esters are synthesized in a highly stereoselective manner via CrCl2-mediated rearrangement of allylic trihalomethylcarbinol esters induced by microwave irradiation.

Original languageEnglish (US)
Pages (from-to)1771-1774
Number of pages4
JournalOrganic and Biomolecular Chemistry
Volume7
Issue number9
DOIs
StatePublished - Apr 20 2009

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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