Influence of deuteration in the glassing matrix on 13C dynamic nuclear polarization

Lloyd Lumata, Matthew E. Merritt, Zoltan Kovacs

Research output: Contribution to journalArticle

40 Scopus citations

Abstract

Replacement of protons by deuterons in the glassing solvents led to 2-3-fold improvement of the 13C dynamic nuclear polarization (DNP) solid-state NMR signal for samples doped with large electron spin resonance (ESR) linewidth free radicals galvinoxyl, DPPH, and 4-oxo-TEMPO. Meanwhile, the reverse effect is observed for 13C DNP using small ESR linewidth free radicals BDPA and trityl OX063.

Original languageEnglish (US)
Pages (from-to)7032-7035
Number of pages4
JournalPhysical Chemistry Chemical Physics
Volume15
Issue number19
DOIs
StatePublished - 2013

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Influence of deuteration in the glassing matrix on <sup>13</sup>C dynamic nuclear polarization'. Together they form a unique fingerprint.

  • Cite this