Mechanistic Basis for the Iridium-Catalyzed Enantioselective Allylation of Alkenyl Boronates

Engineering & Materials Science

• Allylation 100%
• Iridium 60%
• Nucleophiles 56%
• Carbonates 46%
• Stereoselectivity 28%
• Stereochemistry 25%
• Enantiomers 23%
• Ligands 18%
• Reagents 16%
• Esters 14%
• Discrete Fourier transforms 14%
• Catalysts 11%
• Substrates 9%

Medicine & Life Sciences

• Iridium 65%
• Carbonates 58%
• phosphoramidite 25%
• Density Functional Theory 23%
• Kinetics 19%
• Esters 13%
• Ligands 9%

Chemical Compounds

• Boronate 52%
• Allylation 48%
• Carbonate 16%
• Transition State 11%
• Phosphoramidite 8%
• Stereoselectivity 6%
• Coupling Reaction 6%
• Nucleophile 5%
• Stereochemistry 5%
• Enantiomer 5%
• Density Functional Theory 4%
• Ester 4%
• Catalyst 2%