TY - JOUR
T1 - Nucleophilic reactions of heterylsilanes and heterylgermanes (review)
AU - Lukevits, E.
AU - Borisova, L.
AU - Gevorgyan, V.
PY - 1993/7
Y1 - 1993/7
N2 - We generalize data on the reactivity of furyl-, dihydrofuryl-, tetrahydrofuryl-, dihydropyranyl-, and tetrahydropyranylsilanes and -germanes in reactions with nucleophilic reagents. We show that upon reaction of heterosilanes and heterogermanes with O-, N-, C-, and H-nucleophiles, sequential substitution of the heterocycles occurs at the nucleophilic group. We consider the rearrangement of (2-tetrahydrofuryl)- and (2-tetrahydropyranyl) hydrosilanes with ring expansion, and also rearrangement of linear acyloxymethyl- and halomethylhydrosilanes to the corresponding acyloxy- and halosilanes.
AB - We generalize data on the reactivity of furyl-, dihydrofuryl-, tetrahydrofuryl-, dihydropyranyl-, and tetrahydropyranylsilanes and -germanes in reactions with nucleophilic reagents. We show that upon reaction of heterosilanes and heterogermanes with O-, N-, C-, and H-nucleophiles, sequential substitution of the heterocycles occurs at the nucleophilic group. We consider the rearrangement of (2-tetrahydrofuryl)- and (2-tetrahydropyranyl) hydrosilanes with ring expansion, and also rearrangement of linear acyloxymethyl- and halomethylhydrosilanes to the corresponding acyloxy- and halosilanes.
UR - http://www.scopus.com/inward/record.url?scp=34249773356&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=34249773356&partnerID=8YFLogxK
U2 - 10.1007/BF00528884
DO - 10.1007/BF00528884
M3 - Review article
AN - SCOPUS:34249773356
SN - 0009-3122
VL - 29
SP - 735
EP - 743
JO - Chemistry of Heterocyclic Compounds
JF - Chemistry of Heterocyclic Compounds
IS - 7
ER -