Optically active allenes from an allylic substitution/isomerization sequence

Wenhan Zhang, Joseph M. Ready

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

It takes two to trisubstitute: A two-step procedure involving enantioselective allylic alkylation followed by 1,3 hydrogen shift enables the catalytic asymmetric synthesis of trisubstituted allenes.

Original languageEnglish (US)
Pages (from-to)3497-3498
Number of pages2
JournalChemCatChem
Volume5
Issue number12
DOIs
StatePublished - Dec 2013

Fingerprint

alkylation
Alkylation
Isomerization
isomerization
Hydrogen
Substitution reactions
substitutes
shift
hydrogen
synthesis
propadiene

Keywords

  • asymmetric catalyst
  • chiral allene
  • copper
  • enantioselective allylic substitution
  • N-heterocyclic carbenes

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

Optically active allenes from an allylic substitution/isomerization sequence. / Zhang, Wenhan; Ready, Joseph M.

In: ChemCatChem, Vol. 5, No. 12, 12.2013, p. 3497-3498.

Research output: Contribution to journalArticle

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