Origin of enantioselectivity in the jacobsen epoxidation of olefins

Laszlo Kurti; Megan M. Blewett; E. J. Corey

doi:10.1021/ol901859d

Origin of enantioselectivity in the jacobsen epoxidation of olefins

Laszlo Kurti, Megan M. Blewett, E. J. Corey

Biochemistry

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

It Is proposed that facial selectivity In the Jacobsen epoxldatlon Is determined by electrostatic and sterlc factors with a two-step pathway Involving a carbocatlonlc Intermediate.

Original language	English (US)
Pages (from-to)	4592-4595
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	20
DOIs	https://doi.org/10.1021/ol901859d
State	Published - Oct 15 2009

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol901859d

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title = "Origin of enantioselectivity in the jacobsen epoxidation of olefins",

abstract = "It Is proposed that facial selectivity In the Jacobsen epoxldatlon Is determined by electrostatic and sterlc factors with a two-step pathway Involving a carbocatlonlc Intermediate.",

author = "Laszlo Kurti and Blewett, {Megan M.} and Corey, {E. J.}",

year = "2009",

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journal = "Organic Letters",

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AU - Kurti, Laszlo

AU - Blewett, Megan M.

AU - Corey, E. J.

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Y1 - 2009/10/15

N2 - It Is proposed that facial selectivity In the Jacobsen epoxldatlon Is determined by electrostatic and sterlc factors with a two-step pathway Involving a carbocatlonlc Intermediate.

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JO - Organic Letters

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ER -

Origin of enantioselectivity in the jacobsen epoxidation of olefins

Abstract

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