Palladium mediated allylic mitsunobu displacement: stereocontrolled synthesis of hepoxilin A3 and trioxilin A3 methyl esters

Sun Lumin; J R Falck; Jorge Capdevila; Armando Karara

doi:10.1016/0040-4039(92)88148-X

Palladium mediated allylic mitsunobu displacement: stereocontrolled synthesis of hepoxilin A₃ and trioxilin A₃ methyl esters

Sun Lumin, J R Falck, Jorge Capdevila, Armando Karara

Biochemistry

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

A regio- and stereoselective palladium mediated allylic displacement under Mitsunobu conditions was exploited for the preparation of several hepoxilin A₃ and trioxilin A₃ stereoisomers.

Original language	English (US)
Pages (from-to)	2091-2094
Number of pages	4
Journal	Tetrahedron Letters
Volume	33
Issue number	16
DOIs	https://doi.org/10.1016/0040-4039(92)88148-X
State	Published - Apr 14 1992

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(92)88148-X

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title = "Palladium mediated allylic mitsunobu displacement: stereocontrolled synthesis of hepoxilin A3 and trioxilin A3 methyl esters",

abstract = "A regio- and stereoselective palladium mediated allylic displacement under Mitsunobu conditions was exploited for the preparation of several hepoxilin A3 and trioxilin A3 stereoisomers.",

author = "Sun Lumin and Falck, {J R} and Jorge Capdevila and Armando Karara",

note = "Funding Information: Acknowledgment: Supportedb y grants from the USPHS NM (DK-38226) and the Robert A. Welch Foundation( I-782). Funds for the purchaseo f a masss pectrometewr ere providedb y NM (SlO RR05922). Prof. SpencerK napp is thankedfo r manyh elpfuld iscussions.",

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doi = "10.1016/0040-4039(92)88148-X",

language = "English (US)",

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T1 - Palladium mediated allylic mitsunobu displacement

T2 - stereocontrolled synthesis of hepoxilin A3 and trioxilin A3 methyl esters

AU - Lumin, Sun

AU - Falck, J R

AU - Capdevila, Jorge

AU - Karara, Armando

N1 - Funding Information: Acknowledgment: Supportedb y grants from the USPHS NM (DK-38226) and the Robert A. Welch Foundation( I-782). Funds for the purchaseo f a masss pectrometewr ere providedb y NM (SlO RR05922). Prof. SpencerK napp is thankedfo r manyh elpfuld iscussions.

PY - 1992/4/14

Y1 - 1992/4/14

N2 - A regio- and stereoselective palladium mediated allylic displacement under Mitsunobu conditions was exploited for the preparation of several hepoxilin A3 and trioxilin A3 stereoisomers.

AB - A regio- and stereoselective palladium mediated allylic displacement under Mitsunobu conditions was exploited for the preparation of several hepoxilin A3 and trioxilin A3 stereoisomers.

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DO - 10.1016/0040-4039(92)88148-X

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 16

ER -

Palladium mediated allylic mitsunobu displacement: stereocontrolled synthesis of hepoxilin A₃ and trioxilin A₃ methyl esters

Abstract

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