Pd-catalyzed modifiable silanol-directed aromatic C-H oxygenation

Chunhui Huang; Nugzar Ghavtadze; Benhur Godoi; Vladimir Gevorgyan

doi:10.1002/chem.201201616

Pd-catalyzed modifiable silanol-directed aromatic C-H oxygenation

Chunhui Huang, Nugzar Ghavtadze, Benhur Godoi, Vladimir Gevorgyan

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Directing group: A Pd-catalyzed aromatic C-H oxygenation has been developed, featuring a modifiable silanol-directing group. The resulting oxasilacycles can be efficiently modified into a variety of valuable building blocks (see scheme).

Original language	English (US)
Pages (from-to)	9789-9792
Number of pages	4
Journal	Chemistry - A European Journal
Volume	18
Issue number	32
DOIs	https://doi.org/10.1002/chem.201201616
State	Published - Aug 6 2012
Externally published	Yes

Keywords

C-H activation
oxygenation
palladium
silanol
synthetic methods

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201201616

Cite this

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title = "Pd-catalyzed modifiable silanol-directed aromatic C-H oxygenation",

abstract = "Directing group: A Pd-catalyzed aromatic C-H oxygenation has been developed, featuring a modifiable silanol-directing group. The resulting oxasilacycles can be efficiently modified into a variety of valuable building blocks (see scheme).",

keywords = "C-H activation, oxygenation, palladium, silanol, synthetic methods",

author = "Chunhui Huang and Nugzar Ghavtadze and Benhur Godoi and Vladimir Gevorgyan",

year = "2012",

month = aug,

day = "6",

doi = "10.1002/chem.201201616",

language = "English (US)",

volume = "18",

pages = "9789--9792",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "32",

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TY - JOUR

T1 - Pd-catalyzed modifiable silanol-directed aromatic C-H oxygenation

AU - Huang, Chunhui

AU - Ghavtadze, Nugzar

AU - Godoi, Benhur

AU - Gevorgyan, Vladimir

PY - 2012/8/6

Y1 - 2012/8/6

N2 - Directing group: A Pd-catalyzed aromatic C-H oxygenation has been developed, featuring a modifiable silanol-directing group. The resulting oxasilacycles can be efficiently modified into a variety of valuable building blocks (see scheme).

AB - Directing group: A Pd-catalyzed aromatic C-H oxygenation has been developed, featuring a modifiable silanol-directing group. The resulting oxasilacycles can be efficiently modified into a variety of valuable building blocks (see scheme).

KW - C-H activation

KW - oxygenation

KW - palladium

KW - silanol

KW - synthetic methods

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U2 - 10.1002/chem.201201616

DO - 10.1002/chem.201201616

M3 - Article

C2 - 22847834

AN - SCOPUS:84864478358

SN - 0947-6539

VL - 18

SP - 9789

EP - 9792

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 32

ER -

Pd-catalyzed modifiable silanol-directed aromatic C-H oxygenation

Abstract

Keywords

ASJC Scopus subject areas

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