Phase modulated Lee-Goldburg magic angle spinning proton nuclear magnetic resonance experiments in the solid state: A bimodal Floquet theoretical treatment

Elena Vinogradov; P. K. Madhu; Shimon Vega

doi:10.1063/1.1408287

Phase modulated Lee-Goldburg magic angle spinning proton nuclear magnetic resonance experiments in the solid state: A bimodal Floquet theoretical treatment

Elena Vinogradov, P. K. Madhu, Shimon Vega

Research output: Contribution to journal › Article › peer-review

102 Scopus citations

Abstract

A comprehensive treatment of phase-modulated Lee-Goldburg experiment was carried out using both average Hamiltonian and Floquet theory. The treatments showed the rationale for replacing the FSLG scheme by the PMLG scheme, together with insights into the intricate interplay between the simultaneous application of the RF pulses and magic angle spinning. The results support the use of the bimodal Floquet approach for understanding all homonuclear decoupling schemes.

Original language	English (US)
Pages (from-to)	8983-9000
Number of pages	18
Journal	Journal of Chemical Physics
Volume	115
Issue number	19
DOIs	https://doi.org/10.1063/1.1408287
State	Published - Nov 15 2001

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "A comprehensive treatment of phase-modulated Lee-Goldburg experiment was carried out using both average Hamiltonian and Floquet theory. The treatments showed the rationale for replacing the FSLG scheme by the PMLG scheme, together with insights into the intricate interplay between the simultaneous application of the RF pulses and magic angle spinning. The results support the use of the bimodal Floquet approach for understanding all homonuclear decoupling schemes.",

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AB - A comprehensive treatment of phase-modulated Lee-Goldburg experiment was carried out using both average Hamiltonian and Floquet theory. The treatments showed the rationale for replacing the FSLG scheme by the PMLG scheme, together with insights into the intricate interplay between the simultaneous application of the RF pulses and magic angle spinning. The results support the use of the bimodal Floquet approach for understanding all homonuclear decoupling schemes.

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Phase modulated Lee-Goldburg magic angle spinning proton nuclear magnetic resonance experiments in the solid state: A bimodal Floquet theoretical treatment

Abstract

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