Abstract
Both isotopes of silver, 107Ag and 109Ag, were simultaneously polarized by dynamic nuclear polarization (DNP), thus allowing large signal enhancements and the NMR characterization of Ag complexes in the millimolar concentration range. Since both isotopes have long relaxation times T 1, the hyperpolarized NMR signal of one isotope could still be observed even after the magnetization of the other isotope had been destroyed by radio-frequency pulses.
Original language | English (US) |
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Pages (from-to) | 525-527 |
Number of pages | 3 |
Journal | Angewandte Chemie - International Edition |
Volume | 51 |
Issue number | 2 |
DOIs | |
State | Published - Jan 9 2012 |
Keywords
- NMR spectroscopy
- dynamic nuclear polarization
- isotopes
- ligands
- silver
ASJC Scopus subject areas
- Catalysis
- General Chemistry