Proton magnetic resonance spectra of ethylene phosphites and ethylene sulfite

Paul Haake, Jean P. McNeal, Elizabeth J. Goldsmith

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

Complete analyses of proton magnetic resonance spectra are reported for three ethylene phosphites and for ethylene sulfite neat, in benzene, and in chloroform. The vicinal H-C-C-H and P-O-C-H coupling constants indicate that the ethylene phosphites appear to prefer twist-envelope conformations. This result may be generally applicable to the conformation of five-membered rings.

Original languageEnglish (US)
Pages (from-to)715-720
Number of pages6
JournalJournal of the American Chemical Society
Volume90
Issue number3
StatePublished - 1968

Fingerprint

Phosphites
Sulfites
Protons
Ethylene
Magnetic Resonance Spectroscopy
Nuclear magnetic resonance
Conformations
Chloroform
Chlorine compounds
Benzene
ethylene

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Proton magnetic resonance spectra of ethylene phosphites and ethylene sulfite. / Haake, Paul; McNeal, Jean P.; Goldsmith, Elizabeth J.

In: Journal of the American Chemical Society, Vol. 90, No. 3, 1968, p. 715-720.

Research output: Contribution to journalArticle

@article{3c0ff12fbe0841b498c9e36fbfae86bc,
title = "Proton magnetic resonance spectra of ethylene phosphites and ethylene sulfite",
abstract = "Complete analyses of proton magnetic resonance spectra are reported for three ethylene phosphites and for ethylene sulfite neat, in benzene, and in chloroform. The vicinal H-C-C-H and P-O-C-H coupling constants indicate that the ethylene phosphites appear to prefer twist-envelope conformations. This result may be generally applicable to the conformation of five-membered rings.",
author = "Paul Haake and McNeal, {Jean P.} and Goldsmith, {Elizabeth J.}",
year = "1968",
language = "English (US)",
volume = "90",
pages = "715--720",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "3",

}

TY - JOUR

T1 - Proton magnetic resonance spectra of ethylene phosphites and ethylene sulfite

AU - Haake, Paul

AU - McNeal, Jean P.

AU - Goldsmith, Elizabeth J.

PY - 1968

Y1 - 1968

N2 - Complete analyses of proton magnetic resonance spectra are reported for three ethylene phosphites and for ethylene sulfite neat, in benzene, and in chloroform. The vicinal H-C-C-H and P-O-C-H coupling constants indicate that the ethylene phosphites appear to prefer twist-envelope conformations. This result may be generally applicable to the conformation of five-membered rings.

AB - Complete analyses of proton magnetic resonance spectra are reported for three ethylene phosphites and for ethylene sulfite neat, in benzene, and in chloroform. The vicinal H-C-C-H and P-O-C-H coupling constants indicate that the ethylene phosphites appear to prefer twist-envelope conformations. This result may be generally applicable to the conformation of five-membered rings.

UR - http://www.scopus.com/inward/record.url?scp=33749591220&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33749591220&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33749591220

VL - 90

SP - 715

EP - 720

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 3

ER -