Proton MAS NMR Spectra at High Magnetic Fields and High Spinning Frequencies: Spectral Simulations Using Floquet Theory

Siddharth Ray, Elena Vinogradov, Gert Jan Boender, Shimon Vega

Research output: Contribution to journalArticle

18 Scopus citations

Abstract

Proton magic angle spinning (MAS) spectra of a model spin system, consisting of six protons, were calculated for different values of the external magnetic field and the spinning frequencies. Floquet theory was used to evaluate these spectra. The reduction of the effective homonuclear dipolar interaction for increasing spinning frequency was investigated. The influence of an increase of the external magnetic field and the spinning frequencies on the linewidths of the centerband spectra is discussed. This Floquet description of the rotating proton spin system will assist us in our calculations of the CPMAS spin dynamics of a low abundant spin interacting with a set of coupled protons.

Original languageEnglish (US)
Pages (from-to)418-426
Number of pages9
JournalJournal of Magnetic Resonance
Volume135
Issue number2
Publication statusPublished - Dec 1998

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ASJC Scopus subject areas

  • Molecular Biology
  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Radiology Nuclear Medicine and imaging
  • Condensed Matter Physics

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