Radical addition of tetrahydrofuran and tetrahydro-2-furanone to alkenylsilanes in the presence of di(t-butyl)peroxide

Vladimir Gevorgyan, Einars Priede, Edvards Liepiņš, Maris Gavars, Edmunds Lukevics

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

β-(Silylethyl)- and γ-(silylpropyl)-tetrahydrofurans and tetrahydro-2-furanones containing alkyl and phenyl groups at the Si atom were obtained by the reactions of tetrahydrofuran (THF) and tetrahydro-2-furanone with vinyl- and allylsilanes in the presence of di(t-butyl) peroxide (DTBP). To reduce the amount of bis-products, the ratio [heterocycle]:[alkenylsilane]:[DTBP] = 80:4:1 was used.

Original languageEnglish (US)
Pages (from-to)333-338
Number of pages6
JournalJournal of Organometallic Chemistry
Volume393
Issue number3
DOIs
StatePublished - Sep 4 1990
Externally publishedYes

Fingerprint

4-Butyrolactone
peroxides
Peroxides
tetrahydrofuran
Furans
Atoms
products
atoms
di-tert-butyl peroxide
allylsilane

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Radical addition of tetrahydrofuran and tetrahydro-2-furanone to alkenylsilanes in the presence of di(t-butyl)peroxide. / Gevorgyan, Vladimir; Priede, Einars; Liepiņš, Edvards; Gavars, Maris; Lukevics, Edmunds.

In: Journal of Organometallic Chemistry, Vol. 393, No. 3, 04.09.1990, p. 333-338.

Research output: Contribution to journalArticle

Gevorgyan, Vladimir ; Priede, Einars ; Liepiņš, Edvards ; Gavars, Maris ; Lukevics, Edmunds. / Radical addition of tetrahydrofuran and tetrahydro-2-furanone to alkenylsilanes in the presence of di(t-butyl)peroxide. In: Journal of Organometallic Chemistry. 1990 ; Vol. 393, No. 3. pp. 333-338.
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