Radical addition of tetrahydrofuran and tetrahydro-2-furanone to alkenylsilanes in the presence of di(t-butyl)peroxide

Vladimir Gevorgyan, Einars Priede, Edvards Liepiņš, Maris Gavars, Edmunds Lukevics

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

β-(Silylethyl)- and γ-(silylpropyl)-tetrahydrofurans and tetrahydro-2-furanones containing alkyl and phenyl groups at the Si atom were obtained by the reactions of tetrahydrofuran (THF) and tetrahydro-2-furanone with vinyl- and allylsilanes in the presence of di(t-butyl) peroxide (DTBP). To reduce the amount of bis-products, the ratio [heterocycle]:[alkenylsilane]:[DTBP] = 80:4:1 was used.

Original languageEnglish (US)
Pages (from-to)333-338
Number of pages6
JournalJournal of Organometallic Chemistry
Volume393
Issue number3
DOIs
StatePublished - Sep 4 1990
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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