@article{058abbcd952f45fb9cffe11227c644d1,
title = "Reactivity of γ-chloro-gem-trichloroalkanes with chromous chloride",
abstract = "CrCl2-mediated condensation of γ-chloro-gem-trichloroalkanes with aldehyde generates homoallylic alcohols through a hydride rearrangement followed by a Nozaki-Hiyama allylation.",
keywords = "Carbene, Chromium, Nozaki-Hiyama allylation, Trichloroalkane",
author = "Steve Tisserand and Romain Bejot and C{\'e}lia Billaud and Li, {De Run} and Falck, {J. R.} and Charles Mioskowski",
note = "Funding Information: This work was supported by the CNRS and the Institut de Recherche Pierre Fabre (S.T.), the Minist{\`e}re d{\'e}l{\'e}gu{\'e} {\`a} l{\textquoteright}Enseignement sup{\'e}rieur et {\`a} la Recherche (R.B.), the Robert A. Welch Foundation and the NIH (GM31278). We thank Dr. B. Rousseau and the CEA for hydrogenation of 5-decyne with D 2 , C. Antheaume and Dr. A. De Cian for NMR and X-ray spectroscopy.",
year = "2006",
month = jul,
day = "17",
doi = "10.1016/j.tetlet.2006.05.045",
language = "English (US)",
volume = "47",
pages = "5177--5180",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "29",
}