Reductive olefination of aldehydes via chromium brook rearrangement

Rachid Baati, Charles Mioskowski, Deb Barma, Rajashaker Kache, J R Falck

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

The combination of CrCl2 and silyl chlorides converts aryl and conjugated aldehydes into olefinic adducts in good to excellent yields. When constrained by structural features, the intermediate vic-diol can be isolated. Available data are consistent with a novel chromium Brook rearrangement.

Original languageEnglish (US)
Pages (from-to)2949-2951
Number of pages3
JournalOrganic Letters
Volume8
Issue number14
DOIs
StatePublished - Jul 6 2006

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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