Rhodium Thiavinyl Carbenes from 1,2,3-Thiadiazoles Enable Modular Synthesis of Multisubstituted Thiophenes

Daria Kurandina, Vladimir Gevorgyan

Research output: Contribution to journalArticlepeer-review

43 Scopus citations

Abstract

The rhodium-catalyzed transannulation reaction between 1,2,3-thiadiazoles and alkynes, proceeding via intermediacy of the previously unknown Rh thiavinyl carbene, toward a highly efficient and regioselective synthesis of up to fully substituted thiophenes is described.

Original languageEnglish (US)
Pages (from-to)1804-1807
Number of pages4
JournalOrganic Letters
Volume18
Issue number8
DOIs
StatePublished - Apr 15 2016
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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