Rhodium(i)-catalyzed N-CN bond cleavage: Intramolecular β-cyanation of styrenes

Rui Wang, J R Falck

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25 Scopus citations

Abstract

We report herein the first example of intramolecular cyanation of a styrene by a rhodium(i)-catalyzed N-CN cleavage reaction. Substituents on the arenes or the styrene alpha-position are tolerated. Our results demonstrate that alkene cyanation can indeed be atom economical. This journal is

Original languageEnglish (US)
Pages (from-to)6516-6518
Number of pages3
JournalChemical Communications
Volume49
Issue number58
DOIs
Publication statusPublished - Jul 25 2013

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ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

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