Room temperature, open-flask C-H arylation of electron-deficient heteroarenes with triazenes: Rapid synthesis of heterobiaryls

Rui Wang, J R Falck

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Aryl triazenes, a source of aryl radicals, were coupled with heteroarenes via C-H functionalization to produce heterobiaryls in moderate to good yields. Couplings proceeded under an open atmosphere at ambient temperature for 3-24 h. Best results were obtained with electron-deficient heteroarenes, while both electron donating and withdrawing substituents in the triazene moieties were tolerated.

Original languageEnglish (US)
Pages (from-to)1029-1034
Number of pages6
JournalOrganic Chemistry Frontiers
Volume1
Issue number9
DOIs
StatePublished - Nov 1 2014

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Triazenes
Electrons
Temperature

ASJC Scopus subject areas

  • Organic Chemistry

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Room temperature, open-flask C-H arylation of electron-deficient heteroarenes with triazenes : Rapid synthesis of heterobiaryls. / Wang, Rui; Falck, J R.

In: Organic Chemistry Frontiers, Vol. 1, No. 9, 01.11.2014, p. 1029-1034.

Research output: Contribution to journalArticle

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