Sila Morita-Baylis-Hillman reaction of cyclopropenes

Stepan Chuprakov; Denis A. Malyshev; Alexander Trofimov; Vladimir Gevorgyan

doi:10.1021/ja077437s

Sila Morita-Baylis-Hillman reaction of cyclopropenes

Stepan Chuprakov, Denis A. Malyshev, Alexander Trofimov, Vladimir Gevorgyan

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

The first example of sila-Morita-Bayis-Hillman reaction between 1-silylcyclopropenes and carbonyl compounds has been demonstrated. This novel phosphine-catalyzed transformation features a 1,3-Brook rearrangement/elimination cascade and provides convenient access to a variety of 1-(silyloxymethyl)cyclopropenes, which are not easily available via traditional methods.

Original language	English (US)
Pages (from-to)	14868-14869
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	48
DOIs	https://doi.org/10.1021/ja077437s
State	Published - Dec 5 2007
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja077437s

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abstract = "The first example of sila-Morita-Bayis-Hillman reaction between 1-silylcyclopropenes and carbonyl compounds has been demonstrated. This novel phosphine-catalyzed transformation features a 1,3-Brook rearrangement/elimination cascade and provides convenient access to a variety of 1-(silyloxymethyl)cyclopropenes, which are not easily available via traditional methods.",

author = "Stepan Chuprakov and Malyshev, {Denis A.} and Alexander Trofimov and Vladimir Gevorgyan",

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AU - Chuprakov, Stepan

AU - Malyshev, Denis A.

AU - Trofimov, Alexander

AU - Gevorgyan, Vladimir

PY - 2007/12/5

Y1 - 2007/12/5

N2 - The first example of sila-Morita-Bayis-Hillman reaction between 1-silylcyclopropenes and carbonyl compounds has been demonstrated. This novel phosphine-catalyzed transformation features a 1,3-Brook rearrangement/elimination cascade and provides convenient access to a variety of 1-(silyloxymethyl)cyclopropenes, which are not easily available via traditional methods.

AB - The first example of sila-Morita-Bayis-Hillman reaction between 1-silylcyclopropenes and carbonyl compounds has been demonstrated. This novel phosphine-catalyzed transformation features a 1,3-Brook rearrangement/elimination cascade and provides convenient access to a variety of 1-(silyloxymethyl)cyclopropenes, which are not easily available via traditional methods.

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Sila Morita-Baylis-Hillman reaction of cyclopropenes

Abstract

ASJC Scopus subject areas

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