Sila Morita-Baylis-Hillman reaction of cyclopropenes

Stepan Chuprakov, Denis A. Malyshev, Alexander Trofimov, Vladimir Gevorgyan

Research output: Contribution to journalArticle

45 Scopus citations

Abstract

The first example of sila-Morita-Bayis-Hillman reaction between 1-silylcyclopropenes and carbonyl compounds has been demonstrated. This novel phosphine-catalyzed transformation features a 1,3-Brook rearrangement/elimination cascade and provides convenient access to a variety of 1-(silyloxymethyl)cyclopropenes, which are not easily available via traditional methods.

Original languageEnglish (US)
Pages (from-to)14868-14869
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number48
DOIs
StatePublished - Dec 5 2007
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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