Solid-State 31P CP-MAS NMR Study of Phosphine Complexes of Mercury(II)

Tim Allman, R. E. Lenkinski

Research output: Contribution to journalArticle

27 Scopus citations

Abstract

The solid-state 31P CP-MAS NMR spectra of several phosphine complexes of mercury(II) with known crystal structures have been measured. In addition, some simple valence bond calculations were performed and an attempt was made to relate calculated s characters of bonding orbitals to the measured Hg-P coupling constants. The correlation predicted by an approximation to the Fermi contact term was not found.

Original languageEnglish (US)
Pages (from-to)3202-3204
Number of pages3
JournalInorganic Chemistry
Volume25
Issue number18
DOIs
StatePublished - Aug 1986

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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