Some gas phase reactions of silicenium ions derived from sym-tetramethyldisiloxane

Colin G. Pitt, Maurice M. Bursey, Dale A. Chatfield, Raymond S. Greenberg

Research output: Contribution to journalArticlepeer-review

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Abstract

Ion cyclotron resonance spectroscopy has been used to study reactions of the silicenium ions, Me2HSiO S +iMeR (R = H and Me), generated from sym-tetramethyldisiloxane in the gas phase. These silicenium ions react with neutral sym-tetramethyldisiloxane by an addition-elimination process, to form the homologous silicenium ions, H(Me2SiO ) +nSiMeR (n = 2 and 3). Analogous addition-elimination products, MeO(Me2SiO)nSiMeR, are derived from their reaction with methanol. Bimolecular adducts are observed in the presence of benzene and anisole, while oxygen abstraction occurs in the presence of anisole and acetone.

Original languageEnglish (US)
Pages (from-to)269-277
Number of pages9
JournalJournal of Organometallic Chemistry
Volume90
Issue number3
DOIs
StatePublished - May 13 1975
Externally publishedYes

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