Structure and orientation of propargyl chloride partially oriented in a nematic mesophase

E. E. Babcock, J. H. Goldstein

Research output: Contribution to journalArticlepeer-review

Abstract

The proton nuclear magnetic resonance spectra, including 13C satellites at natural abundance, of propargyl chloride partially oriented in a nematic phase were analyzed. The direct coupling constants obtained were corrected for harmonic vibrations and used to calculate geometrical and orientational information. A variation in the temperature at which the NMR spectra were recorded had a negligible effect upon the structure. The difference between the vibrationally uncorrected and corrected distance ratios is substantial.

Original languageEnglish (US)
Pages (from-to)247-253
Number of pages7
JournalJournal of Magnetic Resonance (1969)
Volume52
Issue number2
DOIs
StatePublished - Apr 1983

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