Synthesis and structure of silylmethylsilatranes RR′R″SiCH2Si(OCH2CH23N

Vladimir Gevorgyan, Larisa Borisova, Armand Vjater, Juris Popelis, Sergei Belyakov, Edmunds Lukevics

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

New alkoxysilylmethylsilatranes MePhROSiCH2 Si(OCH2CH23N have been obtained from the reaction of silylmethylsilatrane MePhHSiCH2Si(OCH2CH2)3N with alcohols in the presence of H2PtCl6·6H2O. Methylphenylsilylmethylsilatrane (1) reacted with H2O in the presence of Pd to give methylphenyl(silatranylmethylsilanol (6 which was converted to siloxane (7) and germoxane (8). The molecular structures of the silatrane 1 and silanol 6 have been determined by an X-ray diffraction study which revealed the presence of intramolecular OH ... O bond in the latter.

Original languageEnglish (US)
Pages (from-to)73-79
Number of pages7
JournalJournal of Organometallic Chemistry
Volume482
Issue number1-2
DOIs
StatePublished - Nov 29 1994
Externally publishedYes

Keywords

  • Crystal structure
  • Germanium
  • Hydrogen bonding
  • Silatrane
  • Silicon

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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