Synthesis and structure of silylmethylsilatranes RR′R″SiCH2Si(OCH2CH23N

Vladimir Gevorgyan; Larisa Borisova; Armand Vjater; Juris Popelis; Sergei Belyakov; Edmunds Lukevics

doi:10.1016/0022-328X(94)88186-3

Synthesis and structure of silylmethylsilatranes RR′R″SiCH₂Si(OCH₂CH₂₃N

Vladimir Gevorgyan, Larisa Borisova, Armand Vjater, Juris Popelis, Sergei Belyakov, Edmunds Lukevics

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

New alkoxysilylmethylsilatranes MePhROSiCH₂ Si(OCH₂CH₂₃N have been obtained from the reaction of silylmethylsilatrane MePhHSiCH₂Si(OCH₂CH₂)₃N with alcohols in the presence of H₂PtCl₆·6H₂O. Methylphenylsilylmethylsilatrane (1) reacted with H₂O in the presence of Pd to give methylphenyl(silatranylmethylsilanol (6 which was converted to siloxane (7) and germoxane (8). The molecular structures of the silatrane 1 and silanol 6 have been determined by an X-ray diffraction study which revealed the presence of intramolecular OH ... O bond in the latter.

Original language	English (US)
Pages (from-to)	73-79
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	482
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(94)88186-3
State	Published - Nov 29 1994
Externally published	Yes

Keywords

Crystal structure
Germanium
Hydrogen bonding
Silatrane
Silicon

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0022-328X(94)88186-3

Cite this

@article{25f379d0414741b0ac208d5fafe2c6bb,

title = "Synthesis and structure of silylmethylsilatranes RR′R″SiCH2Si(OCH2CH23N",

abstract = "New alkoxysilylmethylsilatranes MePhROSiCH2 Si(OCH2CH23N have been obtained from the reaction of silylmethylsilatrane MePhHSiCH2Si(OCH2CH2)3N with alcohols in the presence of H2PtCl6·6H2O. Methylphenylsilylmethylsilatrane (1) reacted with H2O in the presence of Pd to give methylphenyl(silatranylmethylsilanol (6 which was converted to siloxane (7) and germoxane (8). The molecular structures of the silatrane 1 and silanol 6 have been determined by an X-ray diffraction study which revealed the presence of intramolecular OH ... O bond in the latter.",

keywords = "Crystal structure, Germanium, Hydrogen bonding, Silatrane, Silicon",

author = "Vladimir Gevorgyan and Larisa Borisova and Armand Vjater and Juris Popelis and Sergei Belyakov and Edmunds Lukevics",

year = "1994",

month = nov,

day = "29",

doi = "10.1016/0022-328X(94)88186-3",

language = "English (US)",

volume = "482",

pages = "73--79",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1-2",

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TY - JOUR

T1 - Synthesis and structure of silylmethylsilatranes RR′R″SiCH2Si(OCH2CH23N

AU - Gevorgyan, Vladimir

AU - Borisova, Larisa

AU - Vjater, Armand

AU - Popelis, Juris

AU - Belyakov, Sergei

AU - Lukevics, Edmunds

PY - 1994/11/29

Y1 - 1994/11/29

N2 - New alkoxysilylmethylsilatranes MePhROSiCH2 Si(OCH2CH23N have been obtained from the reaction of silylmethylsilatrane MePhHSiCH2Si(OCH2CH2)3N with alcohols in the presence of H2PtCl6·6H2O. Methylphenylsilylmethylsilatrane (1) reacted with H2O in the presence of Pd to give methylphenyl(silatranylmethylsilanol (6 which was converted to siloxane (7) and germoxane (8). The molecular structures of the silatrane 1 and silanol 6 have been determined by an X-ray diffraction study which revealed the presence of intramolecular OH ... O bond in the latter.

AB - New alkoxysilylmethylsilatranes MePhROSiCH2 Si(OCH2CH23N have been obtained from the reaction of silylmethylsilatrane MePhHSiCH2Si(OCH2CH2)3N with alcohols in the presence of H2PtCl6·6H2O. Methylphenylsilylmethylsilatrane (1) reacted with H2O in the presence of Pd to give methylphenyl(silatranylmethylsilanol (6 which was converted to siloxane (7) and germoxane (8). The molecular structures of the silatrane 1 and silanol 6 have been determined by an X-ray diffraction study which revealed the presence of intramolecular OH ... O bond in the latter.

KW - Crystal structure

KW - Germanium

KW - Hydrogen bonding

KW - Silatrane

KW - Silicon

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