Synthesis and structure revision of nakiterpiosin

Shuanhu Gao, Qiaoling Wang, Chuo Chen

Research output: Contribution to journalArticlepeer-review

105 Scopus citations

Abstract

This manuscript describes a convergent synthesis and the revision of the relative stereochemistry of nakiterpiosin, a marine C-nor-D-homosteroid. Our synthesis features a late-stage carbonylative Stille cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpiosin skeleton efficiently.

Original languageEnglish (US)
Pages (from-to)1410-1412
Number of pages3
JournalJournal of the American Chemical Society
Volume131
Issue number4
DOIs
StatePublished - Feb 4 2009

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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