Abstract
When activated by an acylating agent, pyridine boronic esters react with organometallic reagents to form a dihydropyridine boronic ester. This intermediate allows access to a number of valuable substituted pyridine, dihydropyridine, and piperidine products.
Original language | English (US) |
---|---|
Pages (from-to) | 2205-2209 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 55 |
Issue number | 6 |
DOIs | |
State | Published - Feb 5 2016 |
Fingerprint
Keywords
- allylic compounds
- boron
- heterocycles
- samarium iodide
- synthetic methods
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
Synthesis and utility of dihydropyridine boronic esters. / Panda, Santanu; Coffin, Aaron; Nguyen, Q. Nhu; Tantillo, Dean J.; Ready, Joseph M.
In: Angewandte Chemie - International Edition, Vol. 55, No. 6, 05.02.2016, p. 2205-2209.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and utility of dihydropyridine boronic esters
AU - Panda, Santanu
AU - Coffin, Aaron
AU - Nguyen, Q. Nhu
AU - Tantillo, Dean J.
AU - Ready, Joseph M.
PY - 2016/2/5
Y1 - 2016/2/5
N2 - When activated by an acylating agent, pyridine boronic esters react with organometallic reagents to form a dihydropyridine boronic ester. This intermediate allows access to a number of valuable substituted pyridine, dihydropyridine, and piperidine products.
AB - When activated by an acylating agent, pyridine boronic esters react with organometallic reagents to form a dihydropyridine boronic ester. This intermediate allows access to a number of valuable substituted pyridine, dihydropyridine, and piperidine products.
KW - allylic compounds
KW - boron
KW - heterocycles
KW - samarium iodide
KW - synthetic methods
UR - http://www.scopus.com/inward/record.url?scp=84957842374&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84957842374&partnerID=8YFLogxK
U2 - 10.1002/anie.201510027
DO - 10.1002/anie.201510027
M3 - Article
C2 - 26694785
AN - SCOPUS:84957842374
VL - 55
SP - 2205
EP - 2209
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 6
ER -