Synthesis of 3-(2,5-dihydrofuryl)-silanes and -germanes and their transformations under catalytic hydrogenation conditions

E. Lukevics, V. N. Gevorgyan, Y. S. Goldberg, M. V. Shymanska

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A number of 3-triorganosilyl- and 3-trimethylgermyl-2,5-dihydrofurans have been prepared by the cyclization of 2-triorganosilyl(germyl)-2-butene-1,4-diols obtained from the hydrosilylation and hydrogermylation products of 1,4-bis(trimethylsiloxy)-2-butyne. It has been found that the liquid-phase heterogeneous hydrogenation of these compounds over palladium catalysts is accompanied by simultaneous isomerization and disproportionation to give the corresponding 3-(4,5-dihydrofuryl)-, 3-tetrahydrofuryl- and 3-furyl- derivatives.

Original languageEnglish (US)
Pages (from-to)283-296
Number of pages14
JournalJournal of Organometallic Chemistry
Volume263
Issue number3
DOIs
StatePublished - Mar 13 1984
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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