The first chemo- and regiospecific palladium-catalyzed enyne-diyne [4+2] intermolecular cross-benzannulation: An effective route to polysubstituted benzenes

Vladimir Gevorgyan, Naoki Sadayori, Yoshinori Yamamoto

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

Series of di- and trisubstituted conjugated enynes 3 in the presence of Pd(PPh3)4 catalyst underwent [4+2] cross- benzannulation reaction with conjugated diynes 4 affording polysubstituted benzenes 5 in reasonable to excellent chemical yields. In all cases the cycloaddition reaction proceeded in regio- and chemospecific manner.

Original languageEnglish (US)
Pages (from-to)8603-8604
Number of pages2
JournalTetrahedron Letters
Volume38
Issue number49
DOIs
StatePublished - Dec 8 1997
Externally publishedYes

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Diynes
Cycloaddition
Cross Reactions
Cycloaddition Reaction
Palladium
Benzene
Catalysts

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

The first chemo- and regiospecific palladium-catalyzed enyne-diyne [4+2] intermolecular cross-benzannulation : An effective route to polysubstituted benzenes. / Gevorgyan, Vladimir; Sadayori, Naoki; Yamamoto, Yoshinori.

In: Tetrahedron Letters, Vol. 38, No. 49, 08.12.1997, p. 8603-8604.

Research output: Contribution to journalArticle

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