The relationship between structure and electrochemical properties of porous gas electrodes

R. Chs Burshtein, V. S. Markin, A. G. Pshenichnikov, V. A. Chismadgev, Y. G. Chirkov

Research output: Contribution to journalArticle

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Abstract

The current-density dependence of nickel gas electrodes with different structures on the pressure difference between the gas and the electrolyte has been investigated. The experimental results are explained by assuming an electrodes model which comprises two kinds of pores. According to this model the electrochemical reaction takes place on the surface of macropores free from electrolyte and in the vicinity of the mouth of micropores filled with electrolyte. The current flows through the micropores filled with electrolyte. The problem of capillary equilibrium in porous bodies is considered.

Original languageEnglish (US)
Pages (from-to)773-787
Number of pages15
JournalElectrochimica Acta
Volume9
Issue number6
StatePublished - Jun 1964

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Electrochemical properties
Electrolytes
Gases
Electrodes
Nickel
Current density

ASJC Scopus subject areas

  • Electrochemistry
  • Analytical Chemistry
  • Chemical Engineering(all)

Cite this

Burshtein, R. C., Markin, V. S., Pshenichnikov, A. G., Chismadgev, V. A., & Chirkov, Y. G. (1964). The relationship between structure and electrochemical properties of porous gas electrodes. Electrochimica Acta, 9(6), 773-787.

The relationship between structure and electrochemical properties of porous gas electrodes. / Burshtein, R. Chs; Markin, V. S.; Pshenichnikov, A. G.; Chismadgev, V. A.; Chirkov, Y. G.

In: Electrochimica Acta, Vol. 9, No. 6, 06.1964, p. 773-787.

Research output: Contribution to journalArticle

Burshtein, RC, Markin, VS, Pshenichnikov, AG, Chismadgev, VA & Chirkov, YG 1964, 'The relationship between structure and electrochemical properties of porous gas electrodes', Electrochimica Acta, vol. 9, no. 6, pp. 773-787.
Burshtein RC, Markin VS, Pshenichnikov AG, Chismadgev VA, Chirkov YG. The relationship between structure and electrochemical properties of porous gas electrodes. Electrochimica Acta. 1964 Jun;9(6):773-787.
Burshtein, R. Chs ; Markin, V. S. ; Pshenichnikov, A. G. ; Chismadgev, V. A. ; Chirkov, Y. G. / The relationship between structure and electrochemical properties of porous gas electrodes. In: Electrochimica Acta. 1964 ; Vol. 9, No. 6. pp. 773-787.
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