The relationship between structure and electrochemical properties of porous gas electrodes

R. Chs Burshtein; V. S. Markin; A. G. Pshenichnikov; V. A. Chismadgev; Y. G. Chirkov

doi:10.1016/0013-4686(64)80064-5

The relationship between structure and electrochemical properties of porous gas electrodes

R. Chs Burshtein, V. S. Markin, A. G. Pshenichnikov, V. A. Chismadgev, Y. G. Chirkov

Neurology & Neurotherapeutics

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Abstract

The current-density dependence of nickel gas electrodes with different structures on the pressure difference between the gas and the electrolyte has been investigated. The experimental results are explained by assuming an electrodes model which comprises two kinds of pores. According to this model the electrochemical reaction takes place on the surface of macropores free from electrolyte and in the vicinity of the mouth of micropores filled with electrolyte. The current flows through the micropores filled with electrolyte. The problem of capillary equilibrium in porous bodies is considered.

Original language	English (US)
Pages (from-to)	773-787
Number of pages	15
Journal	Electrochimica Acta
Volume	9
Issue number	6
DOIs	https://doi.org/10.1016/0013-4686(64)80064-5
State	Published - Jun 1964

ASJC Scopus subject areas

General Chemical Engineering
Electrochemistry

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author = "Burshtein, {R. Chs} and Markin, {V. S.} and Pshenichnikov, {A. G.} and Chismadgev, {V. A.} and Chirkov, {Y. G.}",

year = "1964",

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AU - Burshtein, R. Chs

AU - Markin, V. S.

AU - Pshenichnikov, A. G.

AU - Chismadgev, V. A.

AU - Chirkov, Y. G.

PY - 1964/6

Y1 - 1964/6

N2 - The current-density dependence of nickel gas electrodes with different structures on the pressure difference between the gas and the electrolyte has been investigated. The experimental results are explained by assuming an electrodes model which comprises two kinds of pores. According to this model the electrochemical reaction takes place on the surface of macropores free from electrolyte and in the vicinity of the mouth of micropores filled with electrolyte. The current flows through the micropores filled with electrolyte. The problem of capillary equilibrium in porous bodies is considered.

AB - The current-density dependence of nickel gas electrodes with different structures on the pressure difference between the gas and the electrolyte has been investigated. The experimental results are explained by assuming an electrodes model which comprises two kinds of pores. According to this model the electrochemical reaction takes place on the surface of macropores free from electrolyte and in the vicinity of the mouth of micropores filled with electrolyte. The current flows through the micropores filled with electrolyte. The problem of capillary equilibrium in porous bodies is considered.

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EP - 787

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 6

ER -

The relationship between structure and electrochemical properties of porous gas electrodes

Abstract

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