Vanadium-catalyzed C(sp3)-H fluorination reactions

Ji Bao Xia; Yuyong Ma; Chuo Chen

doi:10.1039/c4qo00057a

Vanadium-catalyzed C(sp³)-H fluorination reactions

Ji Bao Xia, Yuyong Ma, Chuo Chen

Research output: Contribution to journal › Article › peer-review

74 Scopus citations

Abstract

Vanadium(iii) oxide catalyzes the direct fluorination of C(sp³)-H groups with Selectfluor. This reaction is operationally simple. The catalyst and the reaction by-product can be removed easily by filtration. Using this method, a fluorine atom can be introduced to the tertiary position of 1,4-cineole and l-menthone selectively.

Original language	English (US)
Pages (from-to)	468-472
Number of pages	5
Journal	Organic Chemistry Frontiers
Volume	1
Issue number	5
DOIs	https://doi.org/10.1039/c4qo00057a
State	Published - Jul 1 2014

ASJC Scopus subject areas

Organic Chemistry

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title = "Vanadium-catalyzed C(sp3)-H fluorination reactions",

abstract = "Vanadium(iii) oxide catalyzes the direct fluorination of C(sp3)-H groups with Selectfluor. This reaction is operationally simple. The catalyst and the reaction by-product can be removed easily by filtration. Using this method, a fluorine atom can be introduced to the tertiary position of 1,4-cineole and l-menthone selectively.",

author = "Xia, {Ji Bao} and Yuyong Ma and Chuo Chen",

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AU - Xia, Ji Bao

AU - Ma, Yuyong

AU - Chen, Chuo

N1 - Publisher Copyright: This journal is © the Partner Organisations 2014.

PY - 2014/7/1

Y1 - 2014/7/1

N2 - Vanadium(iii) oxide catalyzes the direct fluorination of C(sp3)-H groups with Selectfluor. This reaction is operationally simple. The catalyst and the reaction by-product can be removed easily by filtration. Using this method, a fluorine atom can be introduced to the tertiary position of 1,4-cineole and l-menthone selectively.

AB - Vanadium(iii) oxide catalyzes the direct fluorination of C(sp3)-H groups with Selectfluor. This reaction is operationally simple. The catalyst and the reaction by-product can be removed easily by filtration. Using this method, a fluorine atom can be introduced to the tertiary position of 1,4-cineole and l-menthone selectively.

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M3 - Article

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JF - Organic Chemistry Frontiers

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Vanadium-catalyzed C(sp³)-H fluorination reactions

Abstract

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