Versatile reactivity of rhodium-iminocarbenes derived from N-sulfonyl triazoles

Anton V. Gulevich, Vladimir Gevorgyan

Research output: Contribution to journalArticle

227 Scopus citations

Abstract

The migrations of different groups to the metal-carbene center of Rh II-stabilized iminocarbenes that were derived from N-sulfonyl triazoles are discussed (see scheme). The reactivity of these Rh-iminocabenes can be tuned easily by variation of substituents on the parent triazole.

Original languageEnglish (US)
Pages (from-to)1371-1373
Number of pages3
JournalAngewandte Chemie - International Edition
Volume52
Issue number5
DOIs
StatePublished - Jan 28 2013
Externally publishedYes

Keywords

  • carbenes
  • enamines
  • migration
  • rhodium
  • triazoles

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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