Versatile reactivity of rhodium-iminocarbenes derived from N-sulfonyl triazoles

Anton V. Gulevich, Vladimir Gevorgyan

Research output: Contribution to journalArticle

216 Citations (Scopus)

Abstract

The migrations of different groups to the metal-carbene center of Rh II-stabilized iminocarbenes that were derived from N-sulfonyl triazoles are discussed (see scheme). The reactivity of these Rh-iminocabenes can be tuned easily by variation of substituents on the parent triazole.

Original languageEnglish (US)
Pages (from-to)1371-1373
Number of pages3
JournalAngewandte Chemie - International Edition
Volume52
Issue number5
DOIs
StatePublished - Jan 28 2013
Externally publishedYes

Fingerprint

Rhodium
Triazoles
Metals
carbene

Keywords

  • carbenes
  • enamines
  • migration
  • rhodium
  • triazoles

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Versatile reactivity of rhodium-iminocarbenes derived from N-sulfonyl triazoles. / Gulevich, Anton V.; Gevorgyan, Vladimir.

In: Angewandte Chemie - International Edition, Vol. 52, No. 5, 28.01.2013, p. 1371-1373.

Research output: Contribution to journalArticle

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