@article{1f513ccaafc44c2280841313823e56c3,
title = "Visible-Light-Induced Palladium-Catalyzed Generation of Aryl Radicals from Aryl Triflates",
abstract = "A mild visible-light-induced Pd-catalyzed intramolecular C−H arylation of amides is reported. The method operates by cleavage of a C(sp2)-O bond, leading to hybrid aryl Pd-radical intermediates. The following 1,5-hydrogen atom translocation, intramolecular cyclization, and rearomatization steps lead to valuable oxindole and isoindoline-1-one motifs. Notably, this method provides access to products with readily enolizable functional groups that are incompatible with traditional Pd-catalyzed conditions.",
keywords = "homolysis, light-mediated reactions, palladium, radicals, triflates",
author = "Maxim Ratushnyy and Nikita Kvasovs and Sumon Sarkar and Vladimir Gevorgyan and Maxim Ratushnyy and Nikita Kvasovs and Sumon Sarkar and Vladimir Gevorgyan",
note = "Funding Information: This research was supported by the National Institutes of Health (GM120281), National Science Foundation (CHE-1936422), and Welch Foundation (Chair, AT-0041). We thank Prof. Anvar Zakhidov (UTD) and Dr. Alexios Paradimitratos (UTD) for the help with EPR experiments. Funding Information: This research was supported by the National Institutes of Health (GM120281), National Science Foundation (CHE- 1936422), andWelch Foundation (Chair, AT-0041).We thank Prof. Anvar Zakhidov (UTD) and Dr. Alexios Paradimitratos (UTD) for the help with EPR experiments. Publisher Copyright: {\textcopyright} 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",
year = "2020",
doi = "10.1002/ANGE.201915962",
language = "English (US)",
volume = "132",
pages = "10402--10406",
journal = "Advanced Materials",
issn = "0935-9648",
publisher = "Wiley-VCH Verlag",
number = "26",
}